Alternative (κ1-N:η6-arene vs. κ2-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors?-Reference-Cited by-同舟云学术

Alternative (κ1-N:η6-arene vs. κ2-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors?

Published:2019 Issue:23 Volume:48 Page:8317-8326
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tolpygin Aleksei O.¹²³,Shavyrin Andrei S.¹²³,Cherkasov Anton V.¹²³^ORCID,Fukin Georgy K.¹²³,del Rosal Iker⁴⁵⁶⁷⁸,Maron Laurent⁴⁵⁶⁷⁸^ORCID,Trifonov Alexander A.¹²³⁹¹⁰^ORCID

Affiliation:

1. Institute of Organometallic Chemistry of Russian Academy of Sciences

2. Nizhny Novgorod

3. Russia

4. Université de Toulouse

5. INSA

6. UPS

7. CNRS-UMR5215

8. LPCNO

9. Institute of Organoelement compounds of Russian Academy of Sciences

10. Moscow

Abstract

Both ion size and electronic structure of Ln(ii/iii) ion are decisive in the implementation of either κ¹-amido : η⁶-arene or κ²-N,N′ type of coordination of sterically demanding amidinate ligands.

Funder

Russian Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01162E

Reference55 articles.

1. Synthesis, Structure, and Reactivity of Organometallic .pi.-Complexes of the Rare Earths in the Oxidation State Ln3+ with Aromatic Ligands

2. Synthesis and Structural Chemistry of Non-Cyclopentadienyl Organolanthanide Complexes

3. Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design