A fast and simple B–C bond formation in metallacarboranes avoiding halometallacarboranes and transition metal catalysts-Reference-Cited by-同舟云学术

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A fast and simple B–C bond formation in metallacarboranes avoiding halometallacarboranes and transition metal catalysts

Published:2020 Issue:11 Volume:49 Page:3525-3531
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Buades Ana B.¹²³^ORCID,Kelemen Zsolt¹²³,Arderiu Víctor S.¹²³^ORCID,Zaulet Adnana¹²³,Viñas Clara¹²³^ORCID,Teixidor Francesc¹²³^ORCID

Affiliation:

1. Institut de Ciència de Materials de Barcelona – CSIC

2. Barcelona

3. Spain

Abstract

An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time.

Funder

Ministerio de Economía y Competitividad

Generalitat de Catalunya

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04695J

Reference52 articles.

1. R. N. Grimes , Carboranes , US , 3rd edn, 2016

2. Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes

3. Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

4. Methods to produce B–C, B–P, B–N and B–S bonds in boron clusters

5. The Synthesis and Structural Characterization of Polycyclic Derivatives of Cobalt Bis(dicarbollide)(1–)

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