Highly enantioselective zinc/BINOL-catalyzed alkynylation of α-ketoimine ester: a new entry to optically active quaternary α-CF3 α-amino acids-Reference-Cited by-同舟云学术

Highly enantioselective zinc/BINOL-catalyzed alkynylation of α-ketoimine ester: a new entry to optically active quaternary α-CF3 α-amino acids

Published:2011 Issue:19 Volume:47 Page:5587-5589
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Huang Gaochao¹²³⁴⁵,Yang Jie⁶⁷⁵,Zhang Xingang¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organofluorine Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. China

6. Graduate School of Southwest Petroleum University

7. Chengdu 610065

Abstract

An effective method for highly enantioselective alkynylation of ketoimine (α-trifluoromethyl ketoimine ester) has been developed via a zinc/BINOL catalyzed process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2011/CC/C1CC10403A

Reference39 articles.

1. Peptidomimetics for Receptor Ligands?Discovery, Development, and Medical Perspectives

2. Peptides and Peptidomimetics in Medicine, Surgery and Biotechnology

3. β-Peptidic Peptidomimetics

4. Synthetic strategies to α-trifluoromethyl and α-difluoromethyl substituted α-amino acids

5. Synthesis of fluorinated amino acids

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