Palladium-catalyzed synthesis of α-aryl acetophenones from styryl ethers and aryl diazonium salts via regioselective Heck arylation at room temperature-Reference-Cited by-同舟云学术

Palladium-catalyzed synthesis of α-aryl acetophenones from styryl ethers and aryl diazonium salts via regioselective Heck arylation at room temperature

Published:2021 Issue:36 Volume:19 Page:7832-7837
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Venkatesh Rapelly¹,Singh Adesh Kumar¹,Lee Yong Rok²^ORCID,Kandasamy Jeyakumar¹^ORCID

Affiliation:

1. Department of chemistry, Indian Institute of Technology (BHU), Varanasi, Uttar Pradesh-221005

2. School of Chemical Engineering, Yeungnam University, Gyeongsan, 38541 Republic of Korea

Abstract

Synthesis of α-aryl acetophenones from styryl ethers and aryldiazonium salts is described at room temperature. The reaction is catalyzed by palladium acetate in the absence of ligands and base.

Funder

Science and Engineering Research Board

Indian Institute of Technology (BHU) Varanasi

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01503F

Reference61 articles.

1. An Advantageous Route to Oxcarbazepine (Trileptal) Based on Palladium-Catalyzed Arylations Free of Transmetallating Agents