Energy-dependent timescales in the dissociation of diiodothiophene dication

Author:

Kukk Edwin12ORCID,Pihlava Lassi1ORCID,Kooser Kuno13,Stråhlman Christian4ORCID,Maclot Sylvain5ORCID,Kivimäki Antti6ORCID

Affiliation:

1. Department of Physics and Astronomy, University of Turku, FI-20014 Turku, Finland

2. CNRS, Laboratoire de Chimie Physique - Matière et Rayonnement, 4 Pl. Jussieu, 75005, Paris, France

3. Institute of Physics, University of Tartu, W. Ostwaldi 1, EE-50411 Tartu, Estonia

4. Department of Materials Science and Applied Mathematics, Malmö University, SE-20506 Malmö, Sweden

5. Department of Physics, Gothenburg University, Box 100, SE-40530 Gothenburg, Sweden

6. MAX IV Laboratory, Lund University, SE-22100 Lund, Sweden

Abstract

From experimental electron-ion-ion coincidences and simulations, we followed the evolution of three-body fragmentation from secondary towards concerted dissociation as the available energy increased and determined secondary fragmentation times.

Funder

Academy of Finland

Eesti Teadusagentuur

Vetenskapsrådet

VINNOVA

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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