Iron molybdenum nitrilotriacetate and iminodiacetate – spectroscopy, structural characterization and CO2 adsorption

Author:

Wang Si-Yuan123,Dong Xin123,Chen Jun-Fei453,Zhou Zhao-Hui123ORCID

Affiliation:

1. State Key Laboratory for Physical Chemistry of Solid Surfaces and College of Chemistry and Chemical Engineering, Xiamen University

2. Xiamen

3. China

4. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering

5. Ningxia

Abstract

The tetranuclear iron molybdate Na6[(MoO2)2O2Fe2(nta)4]·16H2O (1) and its isomorphous complexes form 2D water layer structures in a modular manner, and a decanuclear heterometallic polymer, [(MoO4)2FeII4FeIII4(ida)8]n (2), contains an interesting cubic 3D microporous structure with a 3.3 Å diameter hole and can adsorb a small amount of CO2.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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