Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes-Reference-Cited by-同舟云学术

Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes

Published:2020 Issue:23 Volume:49 Page:7790-7795
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Markovski Mishel R.¹²³⁴^ORCID,Siidra Oleg I.¹²³⁴⁵^ORCID,Charkin Dmitri O.⁶⁷⁴,Vladimirova Victoria A.¹²³⁴,Tsirlin Alexander A.⁸⁹¹⁰¹¹¹²^ORCID,Grishaev Vasili Yu.⁶⁷⁴

Affiliation:

1. Department of Crystallography

2. St. Petersburg State University

3. 199034 St. Petersburg

4. Russia

5. Institute of Silicate Chemistry

6. Department of Chemistry

7. Moscow State University

8. Experimental Physics VI

9. Center for Electronic Correlations and Magnetism

10. Institute of Physics

11. University of Augsburg

12. 86135 Augsburg

Abstract

A new lithium copper diselenite chloride hydrate, Li₂Se₂O₅(H₂O)_1.5·CuCl₂, was prepared from aqueous solution.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01260B

Reference29 articles.

1. A Synthetic Route toward Layered Materials: Introducing Stereochemically Active Lone-Pairs into Transition Metal Oxohalides

2. Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

3. ‘Layered hydrogenselenite’ I. Synthesis, structure redetermination of [Cu(HSeO3)2(H2O)2] and determination of [Cu(HSeO3)2(NO3)2]2−·2NH4+,NH4NO3. Structural relationships of these complexes with [Cu(HSeO3)2]

4. ‘Layered hydrogenselenites’ II. Synthesis, structure studies and magnetic properties of a novel series of bimetallic hydrogenselenites: [Cu(HSeO3)2MCl2(H2O)4], M(II) = Mn, Co, Ni, Cu, Zn

5. Synthesis, structure and magnetic measurement of a new layered copper hydrogenselenite: [Cu(HSeO3)2]·(NH4)Cl

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