Strong magnetic coupling of spins in Fe(ii) dimers with differently charged thioindigo ligands

Author:

Konarev Dmitri V.123ORCID,Kuzmin Alexey V.423,Batov Mikhail S.12356ORCID,Khasanov Salavat S.423,Otsuka Akihiro7891011ORCID,Yamochi Hideki7891011ORCID,Kitagawa Hiroshi7891011ORCID,Lyubovskaya Rimma N.123

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. Russia

4. Institute of Solid State Physics RAS

5. M. V. Lomonosov Moscow State University

6. Moscow

7. Division of Chemistry

8. Graduate School of Science

9. Kyoto University

10. Kyoto 606-8502

11. Japan

Abstract

Coordination complex of iron(ii) with radical anion and dianion of thioindigo {[2.2.2]cryptand(K+)}2{FeII(TI˙)(TI2−)}2·2C6H4Cl2 (1) is obtained. Complex has two high-spin FeII centers separated by oxygen atoms, and two TI˙ radical anions coordinated to FeII.

Funder

Kyoto University

Japan Science and Technology Corporation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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