cis-Thioindigo (TI) – a new ligand with accessible radical anion and dianion states. Strong magnetic coupling in the {[TI-(μ2-O),(μ-O)]Cp*Cr}2dimers-Reference-Cited by-同舟云学术

cis-Thioindigo (TI) – a new ligand with accessible radical anion and dianion states. Strong magnetic coupling in the {[TI-(μ2-O),(μ-O)]Cp*Cr}2dimers

Published:2017 Issue:41 Volume:46 Page:14365-14372
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Konarev Dmitri V.¹²³^ORCID,Khasanov Salavat S.⁴²³,Shestakov Alexander F.¹²³,Fatalov Alexey M.¹²³⁵⁶,Batov Mikhail S.¹²³⁵⁶^ORCID,Otsuka Akihiro⁷⁸⁹¹⁰¹¹,Yamochi Hideki⁷⁸⁹¹⁰¹¹,Kitagawa Hiroshi⁷⁸⁹¹⁰¹¹^ORCID,Lyubovskaya Rimma N.¹²³

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. 142432 Russia

4. Institute of Solid State Physics RAS

5. Lomonosov Moscow State University

6. Moscow

7. Division of Chemistry

8. Graduate School of Science

9. Kyoto University

10. Kyoto 606-8502

11. Japan

Abstract

A coordination complex containing thioindigo (TI²⁻) dianions and Cr³⁺with a highS= 3/2 spin state and salt {cryptand[2,2,2](Na⁺)}(TI˙⁻) (2) with paramagnetic TI˙⁻radical anions have been studied for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02878D

Reference39 articles.

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2. Indigo - A Natural Pigment for High Performance Ambipolar Organic Field Effect Transistors and Circuits

3. 25th Anniversary Article: Progress in Chemistry and Applications of Functional Indigos for Organic Electronics

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