Enantioselective copper catalysed intramolecular C–H insertion reactions of α-diazo-β-keto sulfones, α-diazo-β-keto phosphine oxides and 2-diazo-1,3-diketones; the influence of the carbene substituent-Reference-Cited by-同舟云学术

Enantioselective copper catalysed intramolecular C–H insertion reactions of α-diazo-β-keto sulfones, α-diazo-β-keto phosphine oxides and 2-diazo-1,3-diketones; the influence of the carbene substituent

Published:2017 Issue:12 Volume:15 Page:2609-2628
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Shiely Amy E.¹²³⁴⁵,Slattery Catherine N.¹²³⁴⁵,Ford Alan¹²³⁴⁵,Eccles Kevin S.¹²³⁴⁵,Lawrence Simon E.¹²³⁴⁵^ORCID,Maguire Anita R.⁶²⁷³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Analytical and Biological Chemistry Research Facility

3. University College Cork

4. Cork

5. Ireland

6. Department of Chemistry and School of Pharmacy

7. Synthesis and Solid State Pharmaceutical Centre

Abstract

Enantioselective C–H insertion reactions are described.

Funder

Irish Research Council

Irish Research Council for Science, Engineering and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00214A

Reference35 articles.

1. Modern Organic Synthesis with α-Diazocarbonyl Compounds

2. Catalytic asymmetric C–H insertion reactions of α-diazocarbonyl compounds

3. M. P. Doyle , M. A.McKervey and T.Ye , Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: From Cyclopropanes to Ylides , Wiley , New York , 1998

4. Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

5. Catalytic Carbene Insertion into C−H Bonds

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