[Ru(triphos)(CH3CN)3](OTf)2 as a homogeneous catalyst for the hydrogenation of biomass derived 2,5-hexanedione and 2,5-dimethyl-furan in aqueous acidic medium
Author:
Affiliation:
1. Department of Chemistry
2. University of Guelph
3. The Guelph-Waterloo Centre for Graduate Work in Chemistry (GWC)2
4. Guelph
5. Canada
Abstract
In aqueous acidic medium a direct hydrogenation of 2,5-dimethylfuran does not take place with the homogeneous [Ru(triphos)]-system opening a pathway to the more valuable 2,5-hexanediol.
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/GC/C7GC01956D
Reference125 articles.
1. PNNL/NREL, ed. T. Werpy and G. Peterson, US Department of Energy, 2004
2. Advances in 5-hydroxymethylfurfural production from biomass in biphasic solvents
3. H. E. Hoydonckx , W. M.van Rhijn, W.van Rhijn, D. E.de Vos and P. A.Jacobs, in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2007
4. Advances in the conversion of glucose and cellulose to 5-hydroxymethylfurfural over heterogeneous catalysts
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