Unexpected ring opening of pyrazolines with activated alkynes: synthesis of 1H-pyrazole-4,5-dicarboxylates and chromenopyrazolecarboxylates

Author:

Kolla Sai Teja12ORCID,Rayala Nageswara Rao1,Sridhar Balasubramanian3,Bhimapaka China Raju12ORCID

Affiliation:

1. Department of Organic Synthesis & Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad-500 007, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Department of Analytical & Structural Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad-500 007, India

Abstract

1H-Pyrazole-4,5-dicarboxylates and chromenopyrazolecarboxylates were prepared by the reaction of pyrazolines with activated alkynes under neat conditions without a catalyst for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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