PEO composite solid polymer electrolytes with the synergistic effect of cryogenic engineering and trace BP nanosheets for nearly room temperature and 4 V class all-solid-state lithium batteries

Author:

Tan Jiewen1ORCID,Wang Zhen1,Cui Jiawu1,Chen Yuhua2,Jia Zhanhui3,Yang Mingyu1,Gemingjiang Naziyila1,Xiao Zichun1ORCID,Wang Xiaowei4,Gao Wangjiang1,Tian Wensheng2,Zhang Chao1,Tang Wei1,Wu Yuping5ORCID

Affiliation:

1. School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, P. R. China

2. State Key Laboratory of Space Power-sources Technology, Shanghai Institute of Space Power-Sources, 2965 Dongchuan Road, Shanghai 200245, P. R. China

3. Center for Advancing Materials Performance from the Nanoscale (CAMP-Nano), State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, China

4. Institute of Materials Research and Engineering, A*STAR, 2 Fusionopolis Way, Innovis, 138634, Singapore

5. School of Energy and Environment, Southeast University, Nanjing 210096, P. R. China

Abstract

A novel PEO-based SPE with a synergistic effect of black phosphorus (BP) nanosheets and a cryogenic method, which can combine the advantages of the fast Li+ pathways of BP nanosheets and the low PEO crystallization of cryogenic method.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Shanxi Provincial Key Research and Development Project

Xi'an Jiaotong University

State Key Laboratory of Solidification Processing

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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