Highly effective Brønsted base/lewis acid cooperative catalysis: a new Cd metal–organic framework for the synthesis of Hantzsch 1,4-DHPs at ambient temperature-Reference-Cited by-同舟云学术

Highly effective Brønsted base/lewis acid cooperative catalysis: a new Cd metal–organic framework for the synthesis of Hantzsch 1,4-DHPs at ambient temperature

Published:2017 Issue:24 Volume:41 Page:15475-15484
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rouhani Farzaneh¹²³⁴⁵,Morsali Ali¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Sciences

3. Tarbiat Modares University

4. Tehran

5. Iran

Abstract

A new 3D metal–organic framework {[Cd₃(BDC)₃(OPP)(DMF)₂]·2DMA}_n (TMU-33) has been synthesized. The performance of the imine functional group of the OPP ligand as a Brønsted base and open Cd site as a Lewis acid in this framework was investigated as cooperative catalyst.

Funder

Tarbiat Modares University

Iran National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ01509G

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1. Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2

2. Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine