The effect of leaving radical on the formation of tetrahydroselenophene by SHi ring closure: an experimental and computational study-Reference-Cited by-同舟云学术

The effect of leaving radical on the formation of tetrahydroselenophene by SHi ring closure: an experimental and computational study

Published:2015 Issue:8 Volume:13 Page:2310-2316
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Hancock Amber N.¹²³⁴⁵,Lobachevsky Sofia¹²³⁴⁵,Haworth Naomi L.⁶²⁷⁸⁹,Coote Michelle L.¹²⁶²⁷,Schiesser Carl H.¹²³⁴⁵

Affiliation:

1. ARC Centre of Excellence for Free Radical Chemistry and Biotechnology

2. Australia

3. School of Chemistry and Bio21 Molecular Science and Biotechnology Institute

4. The University of Melbourne

5. Victoria

6. ARC Centre of Excellence for Electromaterials Science

7. Research School of Chemistry

8. The Australian National University

9. Canberra

Abstract

Competition kinetic studies augmented with laser-flash photolysis and high-level computational techniques [G3(MP2)-RAD], with [COSMO-RS, SMD] and without solvent correction, provide kinetic parameters for the ring closures of a series of 4-(alkylseleno)butyl radicals.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02434F

Reference47 articles.

1. Homolytic substitution at selenium: ring closure of ω-(benzylseleno)alkyl radicals

2. The kinetics of alkyl radical ring closures at selenium: formation of selenane

3. Homolytic substitution by iminyl radical at selenium: A free-radical route to 1,2-benzoselenazoles

4. 7-Selenabicyclo[2.2.1]heptane

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