Gas-phase synthesis of racemic helicenes and their potential role in the enantiomeric enrichment of sugars and amino acids in meteorites

Author:

Kaiser Ralf I.1ORCID,Zhao Long1,Lu Wenchao2ORCID,Ahmed Musahid2ORCID,Evseev Mikhail M.3,Azyazov Valeriy N.3,Mebel Alexander M.4ORCID,Mohamed Rana K.567,Fischer Felix R.567,Li Xiaohu89ORCID

Affiliation:

1. Department of Chemistry, University of Hawaii at Manoa, Honolulu, Hawaii, 96822, USA

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

3. Lebedev Physical Institute, Samara 443011, Russia

4. Department of Chemistry and Biochemistry, Florida International University, Miami, Florida 33199, USA

5. Department of Chemistry, University of California, Berkeley, CA 94720, USA

6. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

7. Kavli Energy Nano Sciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

8. Xinjiang Astronomical Observatory, Chinese Academy of Sciences, Urumqi, Xinjiang 830011, P. R. China

9. Key Laboratory of Radio Astronomy, Chinese Academy of Sciences, Urumqi, Xinjiang 830011, P. R. China

Abstract

Racemic mixtures of [5] and [6]helicenes can form in the gas-phase of the interstellar medium at ultralow temperatures in the absence of reaction barriers via molecular mass growth processes.

Funder

U.S. Department of Energy

Ministry of Science and Higher Education of the Russian Federation

Xinjiang Tianchi Doctoral Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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