Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes
Author:
Affiliation:
1. Department of Chemistry
2. Zhejiang University
3. Zhejiang, China
Abstract
Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1,1-disubstituted aryl alkenes. These novel IPO ligands will likely be of high value for asymmetric transformations with first-row transition metals.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/QO/C4QO00295D
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