Reactions between microhydrated superoxide anions and formic acid

Author:

Ryding Mauritz Johan12345ORCID,Fernández Israel678910ORCID,Uggerud Einar12345ORCID

Affiliation:

1. Mass Spectrometry Laboratory and Centre of Theoretical and Computational Chemistry

2. Department of Chemistry

3. University of Oslo

4. P.O. Box 1033 Blindern

5. NO-0315 Oslo

6. Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada (ORFEO-CINQA)

7. Facultad de Ciencias Químicas

8. Universidad Complutense de Madrid

9. 28040-Madrid

10. Spain

Abstract

Reactions between water clusters containing the superoxide anion, O2˙(H2O)n (n = 0–4), and formic acid, HCO2H, were studied experimentally in vacuo and modelled using quantum chemical methods.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference59 articles.

1. J. E. Bartmess , in NIST Chemistry WebBook, NIST Standard Reference Database Number 69, ed. P. J. Linstrom and W. G. Mallard, National Institute of Standards and Technology, Gaithersburg MD, USA, retrieved 16 January 2017

2. How super is superoxide?

3. Reactivity of HO2/O−2 Radicals in Aqueous Solution

4. Superoxide Ion: Generation and Chemical Implications

5. Nucleophilic Substitution in Reactions between Partially Hydrated Superoxide Anions and Alkyl Halides

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