Forays into rhodium macrocyclic chemistry stabilized by a P2N2 donor set. Activation of dihydrogen and benzene-Reference-Cited by-同舟云学术

Forays into rhodium macrocyclic chemistry stabilized by a P2N2 donor set. Activation of dihydrogen and benzene

Published:2021 Issue:3 Volume:50 Page:899-907
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yeo Alyssa¹²³⁴^ORCID,Sanz Corey A.¹²³⁴^ORCID,Fryzuk Michael D.¹²³⁴^ORCID

Affiliation:

1. University of British Columbia

2. Department of Chemistry

3. Vancouver

4. Canada

Abstract

A lithium–rhodium(i) cyclooctene complex oxidatively adds dihydrogen and benzene to generate lithium–rhodium(iii) dihydride and phenyl-hydride derivatives, respectively.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03688A

Reference31 articles.

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2. Bis(oxazolinylmethyl)pyrrole Derivatives and Their Coordination as Chiral “Pincer” Ligands to Rhodium

3. C–H and H–H bond activation via ligand dearomatization/rearomatization of a PN3P-rhodium(i) complex

4. Cationic mono and dicarbonyl pincer complexes of rhodium and iridium to assess the donor properties of PCcarbeneP ligands

5. Skeletal change in the PNP pincer ligand leads to a highly regioselective alkyne dimerization catalyst

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