Bidentate nitroxide ligands stable toward oxidative redox cycling and their complexes with cerium and lanthanum-Reference-Cited by-同舟云学术

Bidentate nitroxide ligands stable toward oxidative redox cycling and their complexes with cerium and lanthanum

Published:2015 Issue:81 Volume:51 Page:15047-15050
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kim Jee Eon¹²³⁴⁵^ORCID,Carroll Patrick J.¹²³⁴⁵,Schelter Eric J.¹²³⁴⁵

Affiliation:

1. P. Roy and Diana T. Vagelos Laboratories

2. Department of Chemistry

3. University of Pennsylvania

4. Philadelphia

5. USA

Abstract

A redox non-innocent bidentate nitroxide ligand stabilizes a tetravalent cerium cation and subsequently an electron–hole upon the oxidation on the electrochemical time scale.

Funder

Advanced Research Projects Agency - Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC06052D

Reference32 articles.

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2. Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence

3. Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex

4. A Step beyond the Feltham–Enemark Notation: Spectroscopic and Correlated ab Initio Computational Support for an Antiferromagnetically Coupled M(II)–(NO)− Description of Tp*M(NO) (M = Co, Ni)

5. N–N Bond Cleavage of 1,2-Diarylhydrazines and N–H Bond Formation via H-Atom Transfer in Vanadium Complexes Supported by a Redox-Active Ligand

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