P,C-bond cleavage in the ligand sphere of a nickel(ii) complex
Author:
Affiliation:
1. Technische Universität Kaiserslautern
2. Fachbereich Chemie
3. D-67663 Kaiserslautern
4. Germany
5. Karlsruher Institut für Technologie (KIT)
6. Institut für Anorganische Chemie
7. D-76131 Karlsruhe
Abstract
P,C-bond cleavage at a pyrimidinyl ligand results in a pentacoordinate nickel(ii) complex coordinated by a carbanionic ligand.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02158D
Reference73 articles.
1. Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes
2. Activation of Grignard reagents by transition-metal complexes. A new and simple synthesis of trans-stilbenes and polyphenyls
3. Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents with Alkyl Halides and Tosylates: Remarkable Effect of 1,3-Butadienes
4. Ni- or Cu-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Grignard Reagents
5. Amido Pincer Complexes of Nickel(II): Synthesis, Structure, and Reactivity
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1. Nickel-Carbon σ-Bonded Complexes;Comprehensive Organometallic Chemistry IV;2022
2. First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel];Mendeleev Communications;2016-03
3. Coordination of Nickel(II) by 3-(2-(Diphenylphosphanyl)phenyl)-1H-pyrazole;Zeitschrift für anorganische und allgemeine Chemie;2015-08-18
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