Palladium-catalyzed δ-selective reductive Heck reaction of alkenyl carbonyl compounds with aryl iodides and bromides
Author:
Affiliation:
1. College of Chemistry
2. Henan Key Laboratory of Chemical Biology and Organic Chemistry
3. Green Catalysis Center
4. Zhengzhou University
5. Zhengzhou 450001
Abstract
A simple, operationally convenient and highly regioselective palladium-catalyzed reductive Heck reaction of alkenyl carbonyl compounds with aryl iodides and bromides has been developed to afford structurally diverse δ-aryl pentanoic acid derivatives.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00428F
Reference62 articles.
1. The Heck Reaction as a Sharpening Stone of Palladium Catalysis
2. Palladium-Catalyzed Cross-Coupling Reactions: A Powerful Tool for the Synthesis of Agrochemicals
3. Pd Metal Catalysts for Cross-Couplings and Related Reactions in the 21st Century: A Critical Review
4. Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
5. Intermolecular Mizoroki-Heck Reaction of Aliphatic Olefins with High Selectivity for Substitution at the Internal Position
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