An efficient chromium(iii)-catalyzed aerobic oxidation of methylarenes in water for the green preparation of corresponding acids

Author:

Jiang Feng12,Liu Shanshan3,Zhao Wenshu4,Yu Han23ORCID,Yan Likai5ORCID,Wei Yongge2

Affiliation:

1. Key Laboratory of Cardiovascular and Cerebrovascular Disease Prevention and Control, Ministry of Education, Gannan Medical University, Ganzhou, Jiangxi 341000, P.R. China

2. Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China

3. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P.R. China

4. Longhua Hospital, Shanghai University of Traditional Chinese Medicine, Shanghai 200032, P.R. China

5. Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

Abstract

A highly efficient method to oxidize methylarenes to their corresponding acids with a reusable Cr catalyst was developed. Catalysts which can be recycled, green oxidants and solvent make this new methodology environmentally benign and cost-effective.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Ministry of Education of the People's Republic of China

Tsinghua University

Shanghai Institute of Technology

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference63 articles.

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2. Chemoenzymatic synthesis of chiral carboxylic acids via nitriles

3. J.Opgrande , E. E.Brown , M.Hesser and J.Andrews , Kirk-Othmer Encyclopedia of Chemical Technology , Wiley , New York , 5th edn, 2005 , vol. 3 , pp. 625–635

4. Kinetic studies of the oxidation of aromatic compounds by potassium permanganate. Part I. Toluene

5. Kinetic studies of the oxidation of aromatic compounds by potassium permanganate. Part II. Substituted toluenes

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