The inorganic cation-tailored “trapdoor” effect of silicoaluminophosphate zeolite for highly selective CO2 separation

Author:

Wang Xiaohe12345,Yan Nana678910,Xie Miao111213145,Liu Puxu151617185,Bai Pu12345,Su Haopeng12345,Wang Binyu12345,Wang Yunzheng12345,Li Libo151617185ORCID,Cheng Tao111213145ORCID,Guo Peng678910ORCID,Yan Wenfu12345ORCID,Yu Jihong12345ORCID

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

2. College of Chemistry

3. Jilin University

4. Changchun 130012

5. China

6. National Engineering Laboratory for Methanol to Olefins

7. Dalian National Laboratory for Clean Energy

8. Dalian Institute of Chemical Physics

9. Chinese Academy of Sciences

10. Dalian 116023

11. Institute of Functional Nano & Soft Materials (FUNSOM)

12. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices

13. Soochow University

14. Suzhou 215123

15. College of Chemistry and Chemical Engineering

16. Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization

17. Taiyuan University of Technology

18. Taiyuan 030024

Abstract

The sodium form of silicoaluminophosphate RHO zeolite exhibits a pronounced cation-tailored “trapdoor” effect, showing an unprecedented selectivity adsorption separation performance for CO2/CH4 and CO2/N2.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Dalian National Laboratory for Clean Energy

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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