Understanding the structural landscape of Mn-based MOFs formed with hinged pyrazole carboxylate linkers

Author:

Smernik Josephine F.1,Gimeno-Fonquernie Pol1ORCID,Albalad Jorge1ORCID,Jones Tyla S.1,Young Rosemary J.12ORCID,Champness Neil R.23ORCID,Doonan Christian J.1ORCID,Evans Jack D.1ORCID,Sumby Christopher J.1ORCID

Affiliation:

1. Department of Chemistry and the Centre for Advanced Nanomaterials, School of Physics, Chemistry and Earth Sciences, The University of Adelaide, Adelaide, SA 5005, Australia

2. School of Chemistry, The University of Nottingham, Nottingham, UK

3. School of Chemistry, The University of Birmingham, Birmingham, UK

Abstract

Isoreticulation of MOFs made of pyrazole carboxylate linkers and Mn nodes is nontrivial due to linker flexibility and a variety of accessible Mn nodes. The use of tetratopic hinged linkers to form porous 3D MOFs was identified as a viable strategy.

Funder

National Computational Infrastructure

Australian Research Council

Australian Nuclear Science and Technology Organisation

Australian Institute of Nuclear Science and Engineering

University of Adelaide

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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