Investigation into the reactivity of 16-electron complexes Cp#Co(S2C2B10H10) (Cp# = Cp, Cp*) towards methyl diazoacetate and toluenesulphonyl azide-Reference-Cited by-同舟云学术

Investigation into the reactivity of 16-electron complexes Cp#Co(S2C2B10H10) (Cp# = Cp, Cp*) towards methyl diazoacetate and toluenesulphonyl azide

Published:2014 Issue:106 Volume:4 Page:61799-61808
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Zhong Wei¹²³⁴⁵,Xie Mingshi¹²³⁴,Li Yizhi¹²³⁴,Yan Hong¹²³⁴

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. School of Chemistry and Chemical Engineering

3. Nanjing University

4. Nanjing, China

5. College of Biological, Chemical Sciences and Engineering

Abstract

A three-component reaction of the 16-electron half-sandwich complex Cp*Co(S₂C₂B₁₀H₁₀) (2) with both methyl diazoacetate (MDA) and toluenesulphonyl azide (TsN₃) led to the formation of complexes 3 and 4, while a two-component reaction of complex 2 with MDA afforded products 5–7.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA13017K

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