Quantum resonances and roaming dynamics in formaldehyde photodissociation-Reference-Cited by-同舟云学术

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Quantum resonances and roaming dynamics in formaldehyde photodissociation

Published:2022 Issue: Volume:238 Page:249-265
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Foley Casey D.¹,Xie Changjian²³,Guo Hua³^ORCID,Suits Arthur G.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Missouri, Columbia, MO, 65211, USA

2. Institute of Modern Physics, Shaanxi Key Laboratory for Theoretical Physics Frontiers, Northwest University, Xian, Shaanxi, 710127, China

3. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico, 87131, USA

Abstract

Product HCO rovibrational levels that are near-coincident with prepared rovibrational levels in H2CO mediate roaming resonances that impact the roaming, tight-TS and radical yield.

Funder

Army Research Office

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/FD/D2FD00050D

Reference45 articles.

1. Formaldehyde Photochemistry

2. Rotational resonances in the H 2 CO roaming reaction are revealed by detailed correlations

3. Capturing roaming molecular fragments in real time

4. Orbiting resonances in formaldehyde reveal coupling of roaming, radical, and molecular channels

5. Stark level‐crossing spectroscopy of S0 formaldehyde eigenstates at the dissociation threshold

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