Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption-Reference-Cited by-同舟云学术

Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption

Published:2018 Issue:6 Volume:9 Page:1610-1620
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Clarke Ryan M.¹²³⁴^ORCID,Jeen Tiffany¹²³⁴,Rigo Serena¹²³⁴,Thompson John R.¹²³⁴,Kaake Loren G.¹²³⁴,Thomas Fabrice⁵⁶⁷⁸,Storr Tim¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Simon Fraser University

3. Burnaby

4. Canada

5. Départment de Chimie Moléculaire – Chimie Inorganique Redox (CIRE) – UMR CNRS 5250

6. Université Grenoble-Alpes

7. 38041 Grenoble Cedex 9

8. France

Abstract

We detail the rational design of a series of bimetallic bis-ligand radical Ni salen complexes in which the relative orientation of the ligand radical chromophores provides a mechanism to tune the energy of intense intervalence charge transfer (IVCT) bands in the near infrared (NIR) region.

Funder

Natural Sciences and Engineering Research Council of Canada

Mitacs

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04537A

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