Determination of ultra-low concentrations of gaseous 14C-bearing hydrocarbons produced during corrosion of irradiated steel using accelerator mass spectrometry

Author:

Guillemot T.1234ORCID,Salazar G.5674,Cvetković B. Z.1234ORCID,Kunz D.1234,Szidat S.5674ORCID,Wieland E.1234

Affiliation:

1. Paul Scherrer Institute

2. Laboratory for Waste Management

3. 5232 Villigen PSI

4. Switzerland

5. University of Bern

6. Department of Chemistry and Biochemistry & Oeschger Centre for Climate Change Research

7. 3012 Bern

Abstract

Compound specific radiocarbon analysis, based on gas chromatography and accelerator mass spectrometry, was developed to quantify gaseous 14C species released at pico- to femtomolar concentrations during alkaline anoxic corrosion of irradiated steel.

Funder

Seventh Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry

Reference28 articles.

1. Nagra , Nagra Technical Report NTB 16-01 , Nagra , Wettingen, Switzerland , 2016

2. S. T. Horseman , J. J. W.Higgo , J.Alexander and J. F.Harrington , Report CC-96/1 , Nuclear Energy Agency , Paris, France , 1996

3. L. Yu and E.Weetjens , Report ER-108 , SCK·CEN, Mol , Belgium , 2009

4. L. Johnson and B.Schwyn , Nagra Work Report NAB 08-22 , Nagra , Wettingen, Switzerland , 2008

5. Nuclear Decommissioning Authority , Technical Report NDA/RWMD/092 , Harwell Oxford, United Kingdom , 2012

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