Carburized cobalt catalyst for the Fischer–Tropsch synthesis

Author:

Shen Xianfeng12,Luo Dan12,Ma Chenwei12,Suo HaiYun3,Yan Lai3,Zhang Tianfu134ORCID,Liu Xi35,Wen Xiaodong13ORCID,Li Yongwang13,Yang Yong13

Affiliation:

1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, PR China

2. University of Chinese Academy of Sciences, Beijing 100049, PR China

3. National Energy Center for Coal to Liquids, Synfuels China Co., Ltd., Huairou District, Beijing, 101400, PR China

4. SynCat@Beijing, Synfuels China Co., Ltd., Huairou District, Beijing 101407, PR China

5. In situ Center for Physical Science, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan RD. Minhang District, Shanghai, 200240, PR China

Abstract

Catalysts with Co, Co3C, and Co2C phases are synthesized by controlling the carburization time. The catalyst with Co3C phase exhibits the highest activity in FTS reaction. DFT calculations reveal the high intrinsic activity of Co3C.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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