Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction-Reference-Cited by-同舟云学术

Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction

Published:2016 Issue:12 Volume:52 Page:2609-2611
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Shu Tao¹²³⁴,Ni Qijian¹²³⁴,Song Xiaoxiao¹²³⁴,Zhao Kun¹²³⁴,Wu Tianyu¹²³⁴,Puttreddy Rakesh⁵⁶⁷⁸,Rissanen Kari⁵⁶⁷⁸,Enders Dieter¹²³⁴

Affiliation:

1. Institute of Organic Chemistry

2. RWTH Aachen University

3. Aachen

4. Germany

5. Department of Chemistry

6. University of Jyväskylä

7. 40014 Jyväskylä

8. Finland

Abstract

An NHC-catalyzed Michael/Michael/esterification domino reaction via homoenolate/enolate intermediates for the asymmetric synthesis of tetrasubstituted cyclopentanes is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC09581F

Reference54 articles.

1. Total Synthesis of (-)-Aristeromycin

2. Carbocyclic Nucleoside Analogs. 1. Concise Enantioselective Synthesis of Functionalized Cyclopentanes and Formal Total Synthesis of Aristeromycin

3. Travoprost – a new prostaglandin analogue for the treatment of glaucoma

4. Total Synthesis of Pactamycin

5. Enantioselective Synthesis of Pactamycin, a Complex Antitumor Antibiotic

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