Modelling of an aza-Michael reaction from crystalline naphthalene derivatives containing peri–peri interactions: very long N

Modelling of an aza-Michael reaction from crystalline naphthalene derivatives containing peri–peri interactions: very long N–C bonds?

Published:2020 Issue:41 Volume:22 Page:6783-6795
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Bristow Jonathan C.¹²³⁴,Naftalin Isaac¹²³⁴,Cliff Stacey V. A.¹²³⁴,Yang Songjie¹²³⁴,Carravetta Marina⁵⁶⁷⁴^ORCID,Heinmaa Ivo⁸⁹¹⁰¹¹,Stern Raivo⁸⁹¹⁰¹¹^ORCID,Wallis John D.¹²³⁴^ORCID

Affiliation:

1. School of Science and Technology

2. Nottingham Trent University

3. Nottingham NG11 8NS

4. UK

5. School of Chemistry

6. University of Southampton

7. Southampton

8. Laboratory of Chemical Physics

9. National Institute of Chemical Physics and Biophysics

10. Tallinn

11. Estonia

Abstract

A correlation between N–C bond formation and CC bond breaking is constructed from the structures of a family of peri-naphthalenes with a second set of peri substituents.

Funder

Nottingham Trent University

European Regional Development Fund

Eesti Teadusagentuur

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CE/D0CE01137A

Reference63 articles.

1. Direct Observation of the Transition State