Thermally-induced hysteretic valence tautomeric conversions in the solid state via two-step labile electron transfers in manganese-nitronyl nitroxide 2D-frameworks

Author:

Lecourt Constance12345,Izumi Yuuta678910,Khrouz Lhoussain31112413,Toche François12345,Chiriac Rodica12345,Bélanger-Desmarais Nicolas14151617,Reber Christian14151617ORCID,Fabelo Oscar181920,Inoue Katsuya678910ORCID,Desroches Cédric12345,Luneau Dominique12345ORCID

Affiliation:

1. Laboratoire des Multimatériaux et Interfaces

2. UMR CNRS 5615

3. Univ Lyon

4. Université Claude Bernard Lyon 1

5. F-69622 Villeurbanne

6. Department of Chemistry

7. Graduate School of Science and Chirality Research Center (CResCent)

8. Hiroshima University

9. Hiroshima

10. Japan

11. ENS de Lyon

12. CNRS UMR 5182

13. Laboratoire de Chimie

14. Département de chimie

15. Université de Montréal

16. Montréal

17. Canada

18. Institut Laue-Langevin

19. 38042 Grenoble Cedex 9

20. France

Abstract

Solid-state layered structures of manganese(ii)-nitronyl nitroxide 2D-frameworks exhibit two-step valence tautomeric conversions with hysteresis from near room temperature to warmer regions upon varying the intercalated anion types.

Funder

Université Grenoble Alpes

Natural Sciences and Engineering Research Council of Canada

Centre National de la Recherche Scientifique

Japan Society for the Promotion of Science

Hiroshima University

Université Claude Bernard Lyon 1

Simon Fraser University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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