Synthesis of indolo- and pyrrolo[1,2-a]quinoxalinones through a palladium-catalyzed oxidative carbonylation of the C2 position of indole-Reference-Cited by-同舟云学术

Synthesis of indolo- and pyrrolo[1,2-a]quinoxalinones through a palladium-catalyzed oxidative carbonylation of the C2 position of indole

Published:2020 Issue:8 Volume:18 Page:1612-1622
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Chandrasekhar Attoor¹²³⁴^ORCID,Sankararaman Sethuraman¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Madras

3. Chennai-600036

4. India

Abstract

A methodology that involves the Pd-catalyzed direct C(sp2)–H bond carbonylation of the C₂ position of indole has been introduced for the synthesis of indolo[1,2-a]quinoxalin-6(5H)-ones.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/C9OB02703C

Reference78 articles.

1. Metal-Assisted Multicomponent Reactions Involving Carbon Monoxide—Towards Heterocycle Synthesis

2. Palladium-Catalyzed Carbonylation—A Reaction Come of Age

3. Palladium-Catalyzed Carbonylation Reactions of Alkenes and Alkynes

4. Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

5. Pd-catalysed carbonylations: versatile technology for discovery and process chemists

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