Green synthesis of δ-lactam from biomass-derived 4-hydroxy-6-methylpyridin-2(1H)-one

Author:

Wang Yaqin12,Chen Bingfeng3ORCID,Wu Haihong12ORCID,Mei Xuelei12,Zhang Kaili12,Zheng Bingxiao12,Han Wanying12,Xu Jiao12,He Mingyuan12,Han Buxing132ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

2. Institute of Eco-Chongming, 20 Cuiniao Road, Chenjia Town, Chongming District, Shanghai 202162, China

3. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Abstract

The sustainable route for δ-lactam (6-methylpiperidin-2-one: MPO) production has been demonstrated through transfer hydrogenation/hydrogenolysis of aminolysis product of biomass-derived triacetic acid lactone (TAL) with bimetallic Ni-Ru catalyst.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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