Anion-directed structural tuning of two azomethine-derived Zn2+ complexes with optoelectronic recognition of Cu2+ in aqueous medium with anti-cancer activities: from micromolar to femtomolar sensitivity with DFT revelation

Author:

Pandit Nithun Ranjan1,Bej Sourav23ORCID,Das Riyanka23ORCID,Ghosal Nirajan4,Mondal Ananya15,Pal Ranjana4,Ghosh Meenakshi5,Banerjee Priyabrata23,Biswas Biplab1ORCID

Affiliation:

1. Department of Chemistry, Presidency University, 86/1, College Street, Kolkata 700073, India

2. Electric Mobility and Tribology Research Group, CSIR-Central Mechanical Engineering Research Institute, Mahatma Gandhi Avenue, Durgapur 713209, India

3. Academy of Scientific & Innovative Research (AcSIR), AcSIR Headquarters CSIR-HRDC Campus, Postal Staff College Area, Sector 19, Kamla Nehru Nagar, Ghaziabad – 201002, Uttar Pradesh, India

4. Department of Life Sciences, Presidency University, Kolkata-700073, India

5. Vidyasagar College for Women, 39 Sankar Ghosh Lane, Kolkata, 6, West Bengal, India

Abstract

Herein, two novel mononuclear transition metal Zn2+ complexes  have been synthesised using a tridentate clickable Schiff base ligand, HL (2-methyl-2-((pyridin-2-ylmethyl)amino)propan-1-ol) and the polyatomic monoanions N3 and ClO4.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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