Polarized Au(<scp>i</scp>)/Rh(<scp>i</scp>) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation-Reference-Cited by-同舟云学术

Polarized Au(i)/Rh(i) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation

Published:2023 Issue:12 Volume:52 Page:3835-3845
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alférez Macarena G.¹,Moreno Juan J.¹,Maya Celia¹,Campos Jesús¹^ORCID

Affiliation:

1. Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and University of Sevilla, Avenida Américo Vespucio 49, 41092 Sevilla, Spain

Abstract

Tuning the stereoelectronic and chelating properties of a Rh(i) Lewis base affects its reactivity towards Lewis acidic Au(i) fragments. This includes unusual ligand non-innocence, formation of bimetallic adducts and cooperative NH3 activation.

Funder

Agencia de Innovación y Desarrollo de Andalucía

H2020 European Research Council

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00410D

Reference78 articles.

1. Highly Polar Metal-Metal Bonds in “Early-Late” Heterodimetallic Complexes