Li-ion and Na-ion intercalation in layered MnO2 cathodes enabled by using bismuth as a cation pillar

Author:

Kim Matthew A.1,Zimmerer Eric K.1ORCID,Piontkowski Zachary T.2ORCID,Rodriguez Mark A.3ORCID,Schorr Noah B.4ORCID,Wygant Bryan R.4ORCID,Okasinski John S.5ORCID,Chuang Andrew C.5ORCID,Lambert Timothy N.4ORCID,Gallaway Joshua W.1ORCID

Affiliation:

1. Department of Chemical Engineering, Northeastern University, 360 Huntington Avenue, Boston, MA 02115, USA

2. Department of Applied Optical and Plasma Science, Sandia National Laboratories, Albuquerque, New Mexico 87185, USA

3. Materials Characterization and Performance Department, Sandia National Laboratories, Albuquerque, New Mexico 87185, USA

4. Department of Photovoltaics and Materials Technology, Sandia National Laboratories, Albuquerque, New Mexico, 87185, USA

5. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439, USA

Abstract

Layered MnO2 with Bi inserted into the interlayer stabilizes Li-ion and Na-ion cycling. The amount of Bi affects the crystal water in the structure.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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