The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes-Reference-Cited by-同舟云学术

The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes

Published:2016 Issue:5 Volume:45 Page:1886-1890
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fleming James T.¹²³⁴⁵,Ficks Arne¹²³⁴⁵,Waddell Paul G.¹²³⁴⁵,Harrington Ross W.¹²³⁴⁵,Higham Lee J.¹²³⁴⁵

Affiliation:

1. School of Chemistry

2. Bedson Building

3. Newcastle University

4. Newcastle upon Tyne

5. UK

Abstract

A series of enantiopure MOP-phosphonite ligands, with tailored steric profiles, have been synthesised and are proven to be very successful in high-yielding, regio- and enantioselective catalytic hydrosilylation reactions of substituted styrenes, affording important chiral secondary alcohols.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04475H

Reference18 articles.

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3. Chiral Monodentate Phosphine Ligand MOP for Transition-Metal-Catalyzed Asymmetric Reactions

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5. R. M. Hiney , A.Ficks, H.Müller-Bunz, D. G.Gilheany and L. J.Higham, in Organometallic Chemistry, ed. I. J. S. Fairlamb and J. M. Lynam, The Royal Society of Chemistry, Cambridge, 2011, vol. 37, pp. 27–45

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