A facile route to Ru-alkylidenes-Reference-Cited by-同舟云学术

A facile route to Ru-alkylidenes

Published:2014 Issue:7 Volume:43 Page:2710-2712
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

McKinty Adam M.¹²³,Stephan Douglas W.¹²³

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto, Canada

Abstract

Reactions of dithioacetal E(CH₂CH₂S)₂CHR (E = O, S, R = Ph, C₆F₅) and O(C₆H₄S)₂CHPh with either Ru(cod)(cot) or Ru(PPh₃)₃(H)₂ are used to prepare the Ru-alkylidene complexes E(CH₂CH₂S)₂RuCHPh(L), O(C₆H₄S)₂RuCHPh(L) (L = PCy₃, SIMes) in high yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53525H

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