Phenothiazine-based covalent organic frameworks with low exciton binding energies for photocatalysis-Reference-Cited by-同舟云学术

Phenothiazine-based covalent organic frameworks with low exciton binding energies for photocatalysis

Published:2022 Issue:29 Volume:13 Page:8679-8685
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Weitao¹,Wang Haotian¹,Tang Xiaohui¹,Huo Jinlei¹,Su Yan¹,Lu Chuangye¹,Zhang Yujian²^ORCID,Xu Hong³^ORCID,Gu Cheng¹⁴^ORCID

Affiliation:

1. State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, No. 381 Wushan Road, Tianhe District, Guangzhou 510640, P. R. China

2. Department of Chemistry, Zhejiang Normal University, Jinhua 321004, P. R. China

3. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084, P. R. China

4. Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, South China University of Technology, No. 381 Wushan Road, Tianhe District, Guangzhou, 510640, P. R. China

Abstract

We report the construction of phenothiazine-based covalent organic frameworks, which exhibited diverse structures, the feasibility of bandgap engineering, and unprecedented ultralow exciton binding energy of ∼50 meV for photocatalytic polymerization.

Funder

Higher Education Discipline Innovation Project

Natural Science Foundation of Guangdong Province

China Scholarship Council

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Basic and Applied Basic Research Foundation of Guangdong Province

Thousand Young Talents Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry