Anionic oxoborane and thioxoborane molecules supported by a 1,2-bis(imino)acenaphthene ligand
Author:
Affiliation:
1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry
2. Ministry of Education
3. College of Chemistry and Materials Science
4. Northwest University
5. Xi'an 710127
Abstract
The isolable anionic oxoborane and thioxoborane, supported by a Dip-BIAN ligand, contain terminal doubly bonded BE (E = O, S) groups, respectively, in which only the BO group interacts with imidazolium via a hydrogen bond.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01060C
Reference29 articles.
1. Acid–Base Free Main Group Carbonyl Analogues
2. Superseding β‐Diketiminato Ligands: An Amido Imidazoline‐2‐Imine Ligand Stabilizes the Exhaustive Series of B=X Boranes (X=O, S, Se, Te)
3. Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum
4. Comparison of Anionic and Lewis Acid Stabilized N‐Heterocyclic Oxoboranes: Their Facile Synthesis from a Borinic Acid
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