Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon–carbon bonds
Author:
Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ)
2. Barcelona Institute of Science and Technology
3. 43007 Tarragona
4. Spain
5. Departament de QuímicaAnalítica i QuímicaOrgànica
Abstract
The polycyclisation of polyeneynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon–carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings.
Funder
H2020 European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00235A
Reference73 articles.
1. Gold and Platinum Catalysis of Enyne Cycloisomerization
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5. Ligand Effects in Homogeneous Au Catalysis
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