Expanding the (cross-)hyperconjugation of 1,4-disilacyclohexa-2,5-dienes to larger monomers and oligomers: a computational investigation-Reference-Cited by-同舟云学术

Expanding the (cross-)hyperconjugation of 1,4-disilacyclohexa-2,5-dienes to larger monomers and oligomers: a computational investigation

Published:2016 Issue:43 Volume:6 Page:36961-36970
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Denisova Aleksandra V.¹²³⁴⁵,Emanuelsson Rikard⁶⁷²⁸⁴,Ottosson Henrik¹²³⁴⁵

Affiliation:

1. Department of Chemistry – BMC

2. Uppsala University

3. 751 23 Uppsala

4. Sweden

5. Department of Chemistry – Ångström Laboratory

6. Nanotechnology and Functional Materials

7. Department of Engineering Sciences

8. 751 21 Uppsala

Abstract

DFT calculations are used to study molecules that can be regarded as expanded 1,4-disilacyclohexa-2,5-dienes as well as oligomers based on these or 1,4-disilacyclohexa-2,5-diene with the aim to identify systems with extended (cross)-hyperconjugation.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA02732F

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5. Interaction of nonconjugated double bonds

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