Selenium makes the difference: protonation of [FeFe]-hydrogenase mimics with diselenolato ligands
Author:
Affiliation:
1. Institut für Anorganische und Analytische Chemie
2. Friedrich-Schiller-Universität Jena
3. 07743 Jena
4. Germany
5. Chemistry Department
6. Jordan University of Science and Technology
7. Irbid 22110
8. Jordan
Abstract
The synthetic models of the active site of an [FeFe]-hydrogenase containing a Sn atom in the bridgehead of the diselenato ligand, namely [Fe2(CO)6{μ-(SeCH2Se)SnMe2}],3and [Fe2(CO)6{μ-(SeCH2)2SnMe2}],4have been synthesized and characterized by spectroscopic methods.
Funder
German Academic Exchange Service
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00057J
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