Formation and transformation of iron oxy-hydroxide precursor clusters to ferrihydrite-Reference-Cited by-同舟云学术

Formation and transformation of iron oxy-hydroxide precursor clusters to ferrihydrite

Published:2024 Issue:9 Volume:11 Page:3966-3978
ISSN:2051-8153
Container-title:Environmental Science: Nano
language:en
Short-container-title:Environ. Sci.: Nano

Author:

Namayandeh Alireza¹²^ORCID,Borkiewicz Olaf J.³,Sassi Michel⁴^ORCID,Rosso Kevin M.⁴^ORCID,Michel F. Marc¹⁵

Affiliation:

1. Department of Geosciences, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA

2. Department of Earth System Science, Stanford University, Stanford, CA 94305, USA

3. Advanced Photon Source, Argonne National Laboratory, IL 60439, USA

4. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352, USA

5. Division of Nanoscience, Academy of Integrated Science, Virginia Polytechnic Institute and State University Blacksburg, VA 24061, USA

Abstract

Rapid precipitation of iron oxy-hydroxide clusters at pH > 4.5 during hydrolysis can lead to the formation of metastable ferrihydrite while their aging at acidic pH (<2.5) forms stable products such as goethite and lepidocrocite.

Funder

U.S. Department of Energy

Geological Society of America

National Science Foundation

Virginia Polytechnic Institute and State University

Pacific Northwest National Laboratory

Argonne National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/EN/D3EN00930K

Reference100 articles.

1. Occurrence and Constitution of Natural and Synthetic Ferrihydrite, a Widespread Iron Oxyhydroxide

2. F. M.Michel , Total Scattering Studies of Natural and Synthetic Ferrihydrite. In Advanced Applications of Synchrotron Radiation in Clay Science , Clay Minerals Society , 2014 , vol. 19

3. Composition and structural aspects of naturally occurring ferrihydrite

4. R. M.Cornell and U.Schwertmann , The iron oxides: structure, properties, reactions, occurences and uses , compl. rev. and ext. ed. ed., Wiley-VCH , Weinheim , 2003 , vol. 2

5. Nanominerals, Mineral Nanoparticles, and Earth Systems