Reactions of aryl dimethylphosphinothioate esters with anionic oxygen nucleophiles: transition state structure in 70% water–30% ethanol
Author:
Affiliation:
1. Department of Chemistry
2. Imo State University
3. Owerri
4. Nigeria
5. Department of Pure and Industrial Chemistry
6. Nnamdi Azikiwe University
7. Awka
Abstract
Solvent stabilization of initial state (along x, y axis) leads to looser TS (vector z).
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/RA/D0RA10759J
Reference88 articles.
1. A Concerted Mechanism for the Transfer of the Thiophosphinoyl Group from Aryl Dimethylphosphinothioate Esters to Oxyanionic Nucleophiles in Aqueous Solution
2. Catalysis of the ethanolysis of aryl methyl phenyl phosphinate esters by alkali metal ions: transition state structures for uncatalyzed and metal ion-catalyzed reactions
3. Nucleophilic displacement on 4-nitrophenyl dimethyl phosphinate by ethoxide ion: alkali metal ion catalysis and mechanism
4. Physical Organic Perspectives on Phospho Group Transfer From Phosphates and Phosphinates
5. Characterizing Active Site Conformational Heterogeneity along the Trajectory of an Enzymatic Phosphoryl Transfer Reaction
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3. Mapping transition state structures for thiophosphinoyl group transfer between oxyanionic nucleophiles in water and aqueous ethanol solvents;New Journal of Chemistry;2022
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