Fast, efficient, narrowband room-temperature phosphorescence from metal-free 1,2-diketones: rational design and the mechanism

Author:

Tani Yosuke12ORCID,Miyata Kiyoshi3ORCID,Ou Erika1,Oshima Yuya1,Komura Mao1ORCID,Terasaki Morihisa1,Kimura Shuji3,Ehara Takumi3,Kubo Koki3,Onda Ken3ORCID,Ogawa Takuji1ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyama 1-1, Toyonaka, Osaka 560-0043, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 560-8531, Japan

3. Department of Chemistry, Faculty of Science, Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395, Japan

Abstract

Fast room-temperature phosphorescence with high quantum yields up to 38% in solution from metal-free organic 1,2-diketones is reported, along with the mechanism and molecular design principles governing the fast phosphorescence.

Funder

Sumitomo Foundation

Yazaki Memorial Foundation for Science and Technology

Japan Society for the Promotion of Science

Toyota Physical and Chemical Research Institute

Izumi Science and Technology Foundation

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

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