Fluorination activates the basal plane HER activity of ReS2: a combined experimental and theoretical study

Author:

Liu Yonggang12345,Li Haijing678910,Li Junfu1112131415,Ma Xiaoshuang12345,Cui Zhiming161741819ORCID,Gao Daqiang1112131415ORCID,Tang Zhenghua12345ORCID

Affiliation:

1. Guangzhou Key Laboratory for Surface Chemistry of Energy Materials

2. New Energy Research Institute

3. School of Environment and Energy

4. South China University of Technology

5. Guangzhou Higher Education Mega Centre

6. Beijing Synchrotron Radiation Facility

7. Institute of High Energy Physics

8. Chinese Academy of Sciences

9. Beijing 100049

10. People's Republic of China

11. Key Laboratory for Magnetism and Magnetic Materials of MOE

12. Key Laboratory of Special Function Materials and Structure Design

13. Ministry of Education

14. Lanzhou University

15. Lanzhou

16. Key Laboratory of Fuel Cell Technology of Guangdong Province

17. School of Chemistry and Chemical Engineering

18. Guangzhou

19. China

Abstract

In this study, we report that F doping can activate the in-plane HER activity of ReS2 to achieve comparable performance relative to Pt/C. Theoretical calculations reveal that F doping can optimize the ΔGH* and accelerate electron transport to boost the performance.

Funder

Natural Science Foundation of Gansu Province

South China University of Technology

Guangdong Key Laboratory of Fuel Cell Technology

Guangzhou Science, Technology and Innovation Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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