A novel Prins cascade process for the stereoselective synthesis of oxa-bicycles-Reference-Cited by-同舟云学术

A novel Prins cascade process for the stereoselective synthesis of oxa-bicycles

Published:2015 Issue:9 Volume:13 Page:2669-2672
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Subba Reddy B. V.¹²³⁴,Venkateswarlu A.¹²³⁴,Sridevi B.¹²³⁴,Marumudi Kanakaraju⁵²³⁴,Kunwar A. C.⁵²³⁴,Gayatri G.⁶²³⁴

Affiliation:

1. Natural Product Chemistry

2. CSIR-Indian Institute of Chemical Technology

3. Hyderabad-500 007

4. India

5. Centre for NMR and Structural Chemistry

6. Centre for Molecular Modelling

Abstract

E- and Z-9-Methyldeca-3,8-dien-1-ols undergo smooth cyclization with aldehydes in the presence of 20 mol% AgSbF₆ under extremely mild conditions to generate the corresponding oxa-bicycles in good yields with excellent selectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02347A

Reference31 articles.

1. Total Synthesis of Oxacyclic Macrodiolide Natural Products

2. Strategies for the Formation of Tetrahydropyran Rings in the Synthesis of Natural Products

3. The Pseudomonic Acids

4. Mukaiyama Aldol−Prins Cyclization Cascade Reaction: A Formal Total Synthesis of Leucascandrolide A

5. Synthesis of Leucascandrolide A via a Spontaneous Macrolactolization

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